Study on the Macroscopic Properties and Microstructure of High Fly Ash Content Alkali-Activated Fly Ash Slag Concrete Cured at Room Temperature

室温养护高掺量碱激发粉煤灰渣混凝土宏观性能及微观结构研究

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Abstract

Fly ash and granulated blast furnace slag are both bulk industrial solid wastes. Using these two raw materials to completely replace cement and prepare alkali-activated fly ash slag concrete (AAFSC) at room temperature can not only efficiently utilize industrial solid waste and reduce the carbon footprint, but also reduce the economic cost and technical difficulty of construction, which is of great significance for promoting the sustainable development of the concrete industry. In this article, the content of fly ash accounted for 80% of the total precursor (fly ash + slag), and a mixed solution of sodium silicate and sodium hydroxide was used as alkali activator to prepare AAFSC by curing at room temperature. The effects of alkali equivalent and activator modulus on compressive strength, impermeability, water absorption, and microstructure were systematically studied and compared with ordinary Portland cement concrete. The conclusions drawn were as follows. The 7-day compressive strength of AAFSC was lower than that of cement concrete, while its 28-day compressive strength was 104.86% to 131.94% of that of cement concrete. AAFSC exhibited excellent impermeability protection performance. The water absorption rate of AAFSC was lower, with A8M1 having a water absorption rate of 2.13%, which was only 60.86% of cement concrete. Through microscopic analysis, it was found that the alkali-activated fly ash slag cementitious matrix had good bonding with the aggregate, and there existed fly ash particles with different degrees of reaction. The Ca/Si value of AAFSC was smaller than that of cement concrete.

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