Abstract
The treatment of polychlorinated dibenzodioxins and polychlorinated dibenzofurans (PCDD/Fs) in incineration fly ash presents a significant challenge in solid hazardous waste management. This study systematically analyzed the influence mechanisms of multiple factors on the removal efficiency of PCDD/Fs during fly ash pyrolysis. It integrated 4068 datasets conducted between 2010 and 2025 through meta-analysis. Results show that Al(2)O(3), CaO, SiO(2), and Cl in fly ash components enhance the removal efficiency by 14.0%, while Fe(2)O(3) (Content greater than 5.7%) exhibits inhibitory effects. Cd and Cr demonstrate a bimodal response pattern: low/high concentrations promote removal, while medium concentrations inhibit it. Process optimization identified the optimal parameter combination as pyrolysis temperatures of 500-900 °C, residence time of 50-90 min, and a gas flow rate greater than or equal to 400 mL/min. A significant negative correlation was observed between the initial dioxin concentration and removal efficiency. This study established a structural equation modeling (SEM) model to describe how metallic and nonmetallic components, fly ash components, and pyrolysis conditions determine removal efficiency. Fly ash composition was confirmed as the most influential factor (total effect = 0.3194), with fixed carbon and ash content being the most reliable indicators. Among pyrolysis conditions, gas conditions (flow rate, gas type) also significantly affected removal efficiency (total effect = 0.2357). Conversely, nonmetallic components and excessively prolonged pyrolysis time (beyond the window) consistently reduced removal efficiency. These findings provide theoretical support for upgrading fly ash pyrolysis processes toward low-carbon and resource-efficient operations.