Process Development of Fly Ash-Based Geopolymer Mortars in View of the Mechanical Characteristics

从力学性能角度出发,对粉煤灰基地聚合物砂浆的工艺开发进行研究

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Abstract

This study aimed to determine the effects of design parameters, including the liquid/solid ratio (L/S), Na(2)SiO(3)/NaOH weight ratio, and curing temperature, on class F fly ash-based geopolymer composites. For this purpose, two disparate sources of fly ash were supplied from Çatalağzı (FA) and İsken Sugözü (FB) Thermal Power Plants in Turkey. Two different L/S ratios of 0.2 and 0.4 were used. The Na(2)SiO(3)/NaOH ratios in the alkaline solutions were 1, 1.5, 2, 2.5, and 3 by weight for each type of geopolymer mixture. Then, 40 different mixes were cured at two specific temperatures (70 °C and 100 °C) for 24 h and then preserved at room temperature until testing. Thereafter, the physical water absorption properties, apparent porosity, and bulk density were examined at 28 days on the hardened mortars. Additionally, compressive and flexural tests were applied to the geopolymers at 7, 28, and 90 days. It was found that the highest compressive strength was 60.1 MPa for the geopolymer manufactured with an L/S of 0.2 and Na(2)SiO(3)/NaOH ratio of 2. Moreover, the best thermal curing temperature for obtaining optimal strength characteristics was 100 °C for the FB.

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