Abstract
Developing recovery methods from coal mine waste like mudstone and coal fly ash (CFA) is crucial to expanding the alumina supply beyond bauxite. This review explores various approaches for alumina recovery from mudstone and CFA. Six main leaching techniques are discussed-caustic soda, nitric acid, Sulphuric acid, hydrochloric acid, and leaching roasted coal mine wastes. Due to high silica content, these techniques differ from those for bauxite minerals. Alkaline solutions, like sodium and calcium hydroxide, show promise but are cost-intensive. Sulphuric acid, combined with calcium hydroxide or sodium carbonate before roasting, yields efficient results, surpassing 90 % recovery. Microbial extraction also shows promise, but commercialisation faces equipment accessibility challenges. Heat treatment and optimal calcination temperatures are crucial, especially with acid reagents like Sulphuric and hydrochloric acids, preferred for insolubility in silica and better recovery. Sustainable alumina recovery requires further research into economically viable and ecologically friendly technology. This review underscores the need for feasible, high-purity alumina recovery techniques from mudstone and CFA for industrialisation.