Tailoring the epitaxial growth of oriented Te nanoribbon arrays

定制定向 Te 纳米带阵列的外延生长

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作者:Jie Li, Junrong Zhang, Junwei Chu, Liu Yang, Xinxin Zhao, Yan Zhang, Tong Liu, Yang Lu, Cheng Chen, Xingang Hou, Long Fang, Yijun Xu, Junyong Wang, Kai Zhang

Abstract

As an elemental semiconductor, tellurium (Te) has been famous for its high hole-mobility, excellent ambient stability and topological states. Here, we realize the controllable synthesis of horizontal Te nanoribbon arrays (TRAs) with an angular interval of 60°on mica substrates by physical vapor deposition strategy. The growth of Te nanoribbons (TRs) is driven by two factors, where the intrinsic quasi-one-dimensional spiral chain structure promotes the elongation of their length; the epitaxy relationship between [110] direction of Te and [110] direction of mica facilitates the oriented growth and the expansion of their width. The bending of TRs which have not been reported is induced by grain boundary. Field-effect transistors based on TRs demonstrate high mobility and on/off ratio corresponding to 397 cm2 V-1 s-1 and 1.5×105, respectively. These phenomena supply an opportunity to deep insight into the vapor-transport synthesis of low-dimensional Te and explore its underlying application in monolithic integration.

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