Microwave-Assisted Preparation of Hierarchical Porous Carbon Aerogels Derived from Food Wastes for Supercapacitors

利用微波辅助法制备源自食品废料的分级多孔碳气凝胶用于超级电容器

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Abstract

Preparing carbon aerogel in an eco-friendly and inexpensive manner remains a significant challenge. The carbon aerogels derived from food waste (FWCAs) with a three-dimensional connected network structure are successfully synthesized using microwave radiation. The as-prepared FWCA-4 (The KOH/C ratio is 4) has a large specific surface area (1470 m(2)/g), pore volume (0.634 m(3)/g), and a high degree of graphitization. Band-like lattice stripes with a spacing of 0.34 nm, corresponding to the graphite plane, are observed. A high specific capacitance of 314 F/g at 1.0 A/g and an excellent capacitance retention (>90% after 10,000 cycles) make the FWCA-4 suitable for high-performance supercapacitor electrode materials. Furthermore, the specific surface area and pore volume of FWCA-4 are larger and the degree of graphitization is higher than in ordinary porous carbon derived from food waste (FWPC). The assembled symmetrical solid capacitor from FWCA-4 exhibits a maximum energy density of approximately 179.9 W/kg in neutral ion electrolytes. Thus, food waste is successfully used to prepare carbon aerogels through a gelation process using microwave radiation. The recycling of waste biomass is achieved, and the results provide insights for the preparation of carbon aerogels using biomass.

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