Preparation and Anti-Icing Properties of Zirconia Superhydrophobic Coating

氧化锆超疏水涂层的制备及其防冰性能

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Abstract

Zirconia (ZrO(2)) is a ceramic material with high-temperature resistance and good insulating properties. Herein, for the first time, the surface of ZrO(2) was modified with docosanoic acid (DCA) to improve its self-cleaning and hydrophobic properties. This surface modification transformed the surface of ZrO(2) from hydrophilic to superhydrophobic. A two-step spraying method was used to prepare the superhydrophobic surface of ZrO(2) by sequentially applying a primer and a topcoat. The primer was a solution configured using an epoxy resin as the adhesive and polyamide as the curing agent, while the topcoat was a modified ZrO(2) solution. The superhydrophobic surface of ZrO(2) exhibited a contact angle of 154° and a sliding angle of 4°. Scanning electron microscopy, X-ray diffraction, energy-dispersive X-ray spectroscopy, thermogravimetric analysis, and other analytical techniques were used to characterize the prepared zirconia particles and their surfaces. Moreover, results from surface self-cleaning and droplet freezing tests showed that DCA-modified ZrO(2) can be well combined, and its coatings show good self-cleaning and anti-icing properties on TA2 bases.

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