Abstract
Uranium extraction from seawater has attracted worldwide attention due to the massive reserves of uranium. Due to the straightforward synthesis and strong affinity toward uranyl ions (UO(2) (2+)), the amidoxime group shows promise for use in highly efficient uranium capture. However, the low mass transfer efficiency within traditional amidoxime-based adsorbents severely limits the adsorption rate and the utilization of adsorption sites. In this work, a macroporous polyamidoxime (PAO) hydrogel is prepared by yeast-based biological foaming combined with ice crystal dispersion that effectively maintained the yeast activity. The yeast-raised PAO (Y-PAO) adsorbent has numerous bubble-like holes with an average pore diameter >100 µm. These macropores connected with the intrinsic micropores of PAO to construct efficient diffusion channels for UO(2) (2+) provided fast mass transporting channels, leading to the sufficient exposure of hidden binding sites. The maximum adsorption capacity of Y-PAO membrane reached 10.07 mg-U/g-ads, ≈1.54 times higher than that of the control sample. It took only eight days for Y-PAO to reach the saturation adsorption capacity of the control PAO (6.47 mg-U/g-ads, 28 days). Meanwhile, Y-PAO possessed excellent ion selectivity, good reusability, and low cost. Overall, the Y-PAO membrane is a highly promising adsorbent for use in industrial-scale uranium extraction from seawater.