Abstract
Nowadays, researchers are looking for green synthesis methods of polymers that solve the disadvantages of polymerization with different initiators and traditional methods. In this work, the self-polymerization process of benzidine by anodic exfloated graphene oxide Nanosheet electrode (AEGO Nsh) is reported for the first time in the world. The self-polymerization of benzidine onto AEGO Nsh electrode was done by an easy and simple method by anodizing the graphite sheet followed by immersing the AEGO Nsh electrode inside the benzidine monomer dissolved in organic and inorganic acid media. The surface morphology of the self-polymerized benzidine (SPB) onto the AEGO Nsh (SPB/AEGO Nsh) electrode was investigated by phone camera and scanning electron microscope (FE-SEM) imaging. The chemical characterization of the SPB/AEGO Nsh electrode was verified through XPS and ATR-IR analysis. Additionally, the self-polymerization of benzidine onto AEGO Nsh electrodes was confirmed by electrochemical tests using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques. The results from these investigations unequivocally confirm the self-polymerization of benzidine onto the AEGO Nsh electrode.