Abstract
In this study, three types of chiral fluorescent zirconium-based metal-organic framework materials were synthesized using l-dibenzoyl tartaric acid as the chiral modifier by the solvent-assisted ligand incorporation method, which was the porous coordination network yellow material, denoted as PCN-128Y. PCN-128Y-1 and PCN-128Y-2 featured unique chiral selectivity for the Gln enantiomers amongst seven acids and the highly stable luminescence property, which were caused by the heterochiral interaction and aggregation-induced emission. Furthermore, a rapid fluorescence method for the chiral detection of glutamine (Gln) enantiomers was developed. The homochiral crystals of PCN-128Y-1 displayed enantiodiscrimination in the quenching by d-Gln such that the ratio of enantioselectivity was 2.0 in 30 seconds at pH 7.0, according to the Stern-Volmer quenching plots. The detection limits of d- and l-Gln were 6.6 × 10(-4) mol L(-1) and 3.3 × 10(-4) mol L(-1), respectively. Finally, both the maximum adsorption capacities of PCN-128Y-1 for the Gln enantiomers (Q (e(l-Gln)) = 967 mg g(-1); Q (e(d-Gln)) = 1607 mg g(-1)) and the enantiomeric excess value (6.2%) manifested that PCN-128Y-1 had strong adsorption capacity for the Gln enantiomers and higher affinity for d-Gln.