Electrical discharge triggers quasicrystal formation in an eolian dune

放电引发风成沙丘中准晶体的形成

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Abstract

We report the discovery of a dodecagonal quasicrystal Mn(72.3)Si(15.6)Cr(9.7)Al(1.8)Ni(0.6)-composed of a periodic stacking of atomic planes with quasiperiodic translational order and 12-fold symmetry along the two directions perpendicular to the planes-accidentally formed by an electrical discharge event in an eolian dune in the Sand Hills near Hyannis, Nebraska, United States. The quasicrystal, coexisting with a cubic crystalline phase with composition Mn(68.9)Si(19.9)Ni(7.6)Cr(2.2)Al(1.4), was found in a fulgurite consisting predominantly of fused and melted sand along with traces of melted conductor metal from a nearby downed power line. The fulgurite may have been created by a lightning strike that combined sand with material from downed power line or from electrical discharges from the downed power line alone. Extreme temperatures of at least 1,710 °C were reached, as indicated by the presence of SiO(2) glass in the sample. The dodecagonal quasicrystal is an example of a quasicrystal of any kind formed by electrical discharge, suggesting other places to search for quasicrystals on Earth or in space and for synthesizing them in the laboratory.

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