Inward motion of diamond nanoparticles inside an iron crystal

铁晶体内部金刚石纳米颗粒的向内运动

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作者:Yuecun Wang #, Xudong Wang #, Jun Ding #, Beiming Liang, Lingling Zuo, Shaochuan Zheng, Longchao Huang, Wei Xu, Chuanwei Fan, Zhanqiang Duan, Chunde Jia, Rui Zheng, Zhang Liu, Wei Zhang, Ju Li, En Ma, Zhiwei Shan

Abstract

In the absence of externally applied mechanical loading, it would seem counterintuitive that a solid particle sitting on the surface of another solid could not only sink into the latter, but also continue its rigid-body motion towards the interior, reaching a depth as distant as thousands of times the particle diameter. Here, we demonstrate such a case using in situ microscopic as well as bulk experiments, in which diamond nanoparticles ~100 nm in size move into iron up to millimeter depth, at a temperature about half of the melting point of iron. Each diamond nanoparticle is nudged as a whole, in a displacive motion towards the iron interior, due to a local stress induced by the accumulation of iron atoms diffusing around the particle via a short and easy interfacial channel. Our discovery underscores an unusual mass transport mode in solids, in addition to the familiar diffusion of individual atoms.

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