Directed screening and spatial coupling of farnesyl diphosphate synthase for enhancing menaquinone-7 production in Bacillus subtilis

定向筛选和空间耦合法尼基二磷酸合酶以提高枯草芽孢杆菌中甲萘醌-7的产量

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Abstract

BACKGROUND: Menaquinone-7 (MK-7), a highly bioactive form of vitamin K₂ with a long half-life, plays pivotal roles in preventing osteoporosis and cardiovascular diseases. A metabolically balanced MK-7-producing strain, Bacillus subtilis BS016, has been engineered. However, its biosynthetic efficiency remains hindered by bottlenecks, such as low isoprenoid side-chain elongation efficiency. RESULTS: To address this limitation, a thermophilic farnesyl diphosphate (FPP) synthase from Geobacillus stearothermophilus, characterized by high activity and stability, was identified via database mining. This enzyme was modularly assembled with the endogenous hepS-menG-hepT operon in B. subtilis BS016, driven by the strong promoter P(hbs). A synergistic expression cassette was constructed to achieve spatial co-localization of FPP synthesis with downstream isoprenoid side-chain elongation. The resulting engineered strain BS018 achieved a flask yield of 91.1 mg/L, representing an 11% increase, and maintained a stable titer of 87.9 mg/L in a 5-L fermenter. Further optimisation of fermentation conditions (liquid loading, 50 mL/500 mL; initial pH, 7.0; inoculum dose, 8%) ultimately elevated a flask yield to 109.6 mg/L. CONCLUSION: This study demonstrates that the directed screening of high activity heterologous enzymes, combined with the spatial co-assembly of endogenous pathways, can effectively reconstruct and enhance metabolic flux. This integrated strategy, combining directed enzyme screening with spatial pathway assembly, provides a generalizable framework for constructing efficient cell factories not only for vitamin K₂ but also for other high-value terpenoids. SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1186/s12934-026-02930-1.

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