Fabrication, Characterization and Photocatalytic Activity of Copper Oxide Nanowires Formed by Anodization of Copper Foams

通过铜泡沫阳极氧化法制备氧化铜纳米线,并对其表征和光催化活性进行了研究。

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Abstract

In recent paper anodization of copper foams in 0.1 M K(2)CO(3) is reported. Anodization was performed in the voltage range of 5-25 V and in all the cases oxides with a developed surface area were obtained. However, anodizing only at 20 and 25 V resulted in the formation of nanostruc-tures. In all the cases, the products of anodizing consisted of crystalline phases like cuprite (Cu(2)O), tenorite (CuO), parameconite (Cu(4)O(3)) as well as spertiniite (Cu(OH)(2)). Copper foams after ano-dizing were applied as catalysts in the photocatalytic decolorization of a model organic compound such as methylene blue. The highest photocatalytic activity was observed for samples anodized at 25 V and closely followed by samples anodized at 5 V. The anodized copper foams proved to be a useful material in enhancing the photocatalytic efficiency of organic dye decomposition.

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