Palaeoproteomic identification of the original binder and modern contaminants in distemper paints from Uvdal stave church, Norway

挪威乌夫达尔木板教堂水性涂料中原始粘合剂和现代污染物的古蛋白质组学鉴定

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作者:Zahra Haghighi #, Meaghan Mackie #, Anne Apalnes Ørnhøi, Abigail Ramsøe, Tone Marie Olstad, Simon James Armitage, Christopher Stuart Henshilwood, Enrico Cappellini

Abstract

Two distemper paint samples taken from decorative boards in Uvdal stave church, Norway, were analysed using palaeoproteomics, with an aim of identifying their binder and possible contaminants. The results point at the use of calfskin to produce hide glue as the original paint binder, and are consistent with the instructions of binder production and resource allocation in the historical records of Norway. Although we did not observe any evidence of prior restoration treatments using protein-based materials, we found abundant traces of human saliva proteins, as well as a few oats and barley peptides, likely deposited together on the boards during their discovery in the 1970s. This work illustrates the need to fully consider contamination sources in palaeoproteomics and to inform those working with such objects about the potential for their contamination.

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