Fe3O4/Graphene Composite Anode Material for Fast-Charging Li-Ion Batteries

用于快速充电锂离子电池的 Fe3O4/石墨烯复合阳极材料

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作者:Antunes Staffolani, Hamideh Darjazi, Gilberto Carbonari, Fabio Maroni, Serena Gabrielli, Francesco Nobili

Abstract

Composite anode material based on Fe3O4 and reduced graphene oxide is prepared by base-catalysed co-precipitation and sonochemical dispersion. Structural and morphological characterizations demonstrate an effective and homogeneous embedding of Fe3O4 nanoparticles in the carbonaceous matrix. Electrochemical characterization highlights specific capacities higher than 1000 mAh g-1 at 1C, while a capacity of 980 mAhg-1 is retained at 4C, with outstanding cycling stability. These results demonstrate a synergistic effect by nanosize morphology of Fe3O4 and inter-particle conductivity of graphene nanosheets, which also contribute to enhancing the mechanical and cycling stability of the electrode. The outstanding capacity delivered at high rates suggests a possible application of the anode material for high-power systems.

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