Signatures of a magnetic field-induced unconventional nematic liquid in the frustrated and anisotropic spin-chain cuprate LiCuSbO(4)

受挫各向异性自旋链铜酸盐LiCuSbO(4)中磁场诱导非常规向列相液体的特征

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Abstract

Modern theories of quantum magnetism predict exotic multipolar states in weakly interacting strongly frustrated spin-1/2 Heisenberg chains with ferromagnetic nearest neighbor (NN) inchain exchange in high magnetic fields. Experimentally these states remained elusive so far. Here we report strong indications of a magnetic field-induced nematic liquid arising above a field of ~13 T in the edge-sharing chain cuprate LiSbCuO(4) ≡ LiCuSbO(4). This interpretation is based on the observation of a field induced spin-gap in the measurements of the (7)Li NMR spin relaxation rate T (1)(-1) as well as a contrasting field-dependent power-law behavior of T (1)(-1) vs. T and is further supported by static magnetization and ESR data. An underlying theoretical microscopic approach favoring a nematic scenario is based essentially on the NN XYZ exchange anisotropy within a model for frustrated spin-1/2 chains and is investigated by the DMRG technique. The employed exchange parameters are justified qualitatively by electronic structure calculations for LiCuSbO(4).

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