Supramolecular Modification of Graphene Sponge with a Porphyrin Derivative Enhances the Photothermal Conversion Efficiency of a Solar Steam Generator

利用卟啉衍生物对石墨烯海绵进行超分子修饰可提高太阳能蒸汽发生器的光热转换效率

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Abstract

Solar energy seems to be a promising solution for obtaining clean water from saltwater and wastewater. With the solar steam generator system, it is possible to effectively acquire clean water from wastewater with a low-cost, sustainable, and environmentally friendly approach. In this study, PRF/GGSM, prepared by modification of gradient graphene sponge material (GGSM) with porphyrin derivative supramolecules (PRF), was investigated as a photothermal material for solar steam generation. PRF/GGSM possessing graphene and PRF served as ideal solar thermal converters that could easily gather sunlight. This material owing to its microporous and gradient hydrophilic structure has achieved a solar thermal conversion efficiency of up to 92% under 1 sun, corresponding to the water evaporation rate of 3.8 kg h(-1) m(-2). Moreover, this study exhibited that PRF/GGSM can efficiently generate clean water from seawater, wastewater, and even concentrated acid and alkali solutions.

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