Abstract
A novel heterostructured nanocomposite UCNPs@SiO(2)@Ag/g-C(3)N(4) was developed for the first time to substantially boost the solar-light driven photocatalytic activity of g-C(3)N(4). Its photocatalytic properties and photocatalytic mechanism were investigated. The as-synthesized photocatalyst with excellent improvement in the solar absorption and separation efficiency of photoinduced electron-hole pairs exhibited optimum solar-induced photocatalytic activity in dye degradation and hydrogen production. The experimental results showed that the rates of degradation of Rhodamine B (RhB) and hydrogen evolution were about 10 and 12 times higher than that of pristine g-C(3)N(4), respectively. The excellent photocatalytic activity was attributed to the synergetic effect of upconversion nanoparticles (UCNPs) and Ag nanoparticles (NPs) on the modification of the photocatalytic properties of g-C(3)N(4), resulting in a broad light response range for g-C(3)N(4) as well as the fast separation and slow recombination of photoinduced electron-hole pairs. This study provides new insight into the fabrication of g-C(3)N(4)-based nanocomposite photocatalysts with high catalytic efficiency through the artful assembly of UCNPs, Ag NPs and g-C(3)N(4) into a hetero-composite nanostructure. The prominent improvement in photocatalytic activity enables the potential application of g-C(3)N(4) in the photocatalytic degradation of organic pollutants and hydrogen production utilizing solar energy.