Photothermal conversion and geochemical characterization of sulfur-rich lignite for non-conventional energy applications

富硫褐煤的光热转换和地球化学表征及其在非常规能源应用中的价值

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Abstract

Lignite has emerged as a critical material in contemporary energy portfolios, particularly in electricity generation. However, this work explores lignite's potential beyond conventional uses, exploring on its energy conversion applications. In a pioneering move, lignite samples have been directly utilized as materials for photothermal conversion applications, along with a description of their geochemical features, such as sulfur compositions, forms, and microscopic characteristics. Among the twenty lignite samples that were geologically studied, two sulfur-rich samples (CS-1 and CS-2) were chosen to explore their photothermal conversion performance. The powder-XRD diffraction patterns of CS-1 and CS-2 reveal the presence of the hexagonal phase of carbon C(1) with kaolinite (Al(2)Si(2)O(5)(OH)(4)). Their XPS spectra indicate that both organic and metal-bonded sulfide moieties are present in the lignite samples. CS-1 and CS-2 were implemented under 1 Sun irradiation, and it was found that CS-2 exhibits superior light-absorbing properties, resulting in enhanced water evaporation rates. In addition, the photothermal imaging also shows a temperature increase to 58.2 °C within 10 min for lignite-coated membranes, compared to 31 °C for the blank under similar conditions. These findings can be leveraged to explore lignite's untapped potential in various technological domains, propelling the global transition towards cleaner energy solutions.

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