Infrared Efficiency and Ultraviolet Management of Red-Pigmented Polymethylmethacrylate Photoselective Greenhouse Films

红色颜料聚甲基丙烯酸甲酯光选择性温室薄膜的红外效率和紫外线控制

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Abstract

Red-pigmented photoselective polymethylmethacrylate (PMMA) films were prepared by casting from polymer/chloroform solution. The films were doped with efficient red fluorescent perylene dyes specialized for plastic coloration, namely KREMER 94720 and KREMER 94739, which have excellent weathering stability and a high fluorescence quantum yield. The effect of the doping concentration was studied using the atomic force microscope (AFM), optical transmission, color measurement, time-resolved fluorescence, and Fourier transform infrared spectroscopy (FTIR). The obtained results suggested the potential usefulness for photoselective greenhouse cladding applications as the lowest doping concentration (10(-5) wt%) displaying the UV-open effect, whereas the best UV-blocking and thermic effects were obtained for the highest doping concentration (10(-1) wt).

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