Photothermal effectiveness of microporous carbon nanospheres incorporated with polysulfone in direct contact membrane distillation

聚砜掺杂微孔碳纳米球在直接接触式膜蒸馏中的光热效率

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Abstract

Carbon nano-spheres (CNS) were synthesized via a hydrothermal method using d-glucose as a precursor, followed by pyrolysis in a nitrogen atmosphere. The resulting CNS were integrated into polysulfone (PSF) membranes to enhance their photothermal properties. Characterization using various techniques revealed improved thermal properties upon CNS inclusion, with a notable increase in membrane surface temperature and enhancement of contact angle (CA) and liquid entry pressure (LEP). Composite PSF membranes containing varying CNS concentrations (0.25-5%) exhibited optimal performance at 3% CNS concentration, demonstrating enhanced morphological conformation and photothermal attributes. Evaluation under tungsten bulbs light using a photothermal membrane distillation system showed significant improvement in membrane distillation flux, achieving a maximum water flux of 7.73 L m(-2) h(-1) and a salt rejection rate of 99.9%. These findings highlight the potential of hydrothermal CNS in enhancing photothermal properties and membrane performance for applications in desalination and wastewater treatment.

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