Abstract
Biomimetic structures inspired by evolutionary optimized biological systems offer promising solutions to overcome current limitations in passive daytime radiative cooling (PDRC) technology, which efficiently scatters solar radiation through atmospheric windows and radiates surface heat into space without additional energy consumption. While structural biomimicry provides excellent optical performance and feasibility, its complex manufacturing and high costs limit scalability due to micro-nano fabrication constraints. Material-based biomimicry, utilizing environmentally friendly and abundant raw materials, offers greater scalability but requires improvements in mechanical durability. Adaptive biomimicry enables intelligent regulation with high responsiveness but faces challenges in system complexity, stability, and large-scale integration. These biologically derived strategies provide valuable insights for advancing radiative cooling devices. This review systematically summarizes recent progress, elucidates mechanisms of key biological structures for photothermal regulation, and explores their application potential across various fields. It also discusses current challenges and future research directions, aiming to promote deeper investigation and breakthroughs in biomimetic radiative cooling technologies.