Synthesis of core-shell N-TiO(2)@CuO (x) with enhanced visible light photocatalytic performance

合成核壳结构的N-TiO(2)@CuO(x)及其增强的可见光光催化性能

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Abstract

In this paper, a core-shell N-TiO(2)@CuO (x) nanomaterial with increased visible light photocatalytic activity was successfully synthesized using a simple method. By synthesizing ammonium titanyl oxalate as a precursor, N-doped TiO(2) can be prepared, then the core-shell structure of N-TiO(2)@CuO (x) with a catalyst loading of Cu on its surface was prepared using a precipitation method. It was characterized in detail using XRD, TEM, BET, XPS and H(2)-TPR, while its photocatalytic activity was evaluated using the probe reaction of the degradation of methyl orange. We found that the core-shell N-TiO(2)@CuO (x) nanomaterial can lessen the TiO(2) energy band-gap width due to the N-doping, as well as remarkably improving the photo-degradation activity due to a certain loading of Cu on the surfaces of N-TiO(2) supports. Therefore, a preparation method for a novel N, Cu co-doped TiO(2) photocatalyst with a core-shell structure and efficient photocatalytic performance has been provided.

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