Abstract
Photocatalytic H(2) generation holds promise in the green production of alternative fuels and valuable chemicals. Seeking alternative, cost-effective, stable, and possibly reusable catalysts represents a timeless challenge for scientists working in the field. Herein, commercial RuO(2) nanostructures were found to be a robust, versatile, and competitive catalyst in H(2) photoproduction in several conditions. We employed it in a classic three-component system and compared its activities with those of the widely used platinum nanoparticle catalyst. We observed a hydrogen evolution rate of 0.137 mol h(-1) g(-1) and an apparent quantum efficiency (AQE) of 6.8% in water using EDTA as an electron donor. Moreover, the favorable employment of l-cysteine as the electron source opens possibilities precluded to other noble metal catalyst. The versatility of the system has also been demonstrated in organic media with impressive H(2) production in acetonitrile. The robustness has been proved by the recovery of the catalyst by centrifugation and reusage alternatively in different media.