Abstract
Various conversion routes of biomass and its derivative compounds into high-value products has attracted attention from researchers recently. Among these, a solar-driven photoelectrochemical (PEC) oxidation approach of biomass alcohols to aldehydes is particularly of great interest for the potential applications because the reaction is selective and simultaneously accompanied with hydrogen production. Here, we propose a simulation of selective oxidation of benzyl alcohol into benzaldehyde coupled with hydrogen production in a 2-dimensional continuous-flow PEC reactor using COMSOL Multiphysics (5.6). In order to develop and fabricate a simple yet efficient reactor for a practical use, it is crucial to investigate the effects of operating and design parameters of the reactor on the reactions. Our studies demonstrated that the main contributions to product formation were the electrolyte flow velocity and the width of electrolyte channels. The optimized design parameter exhibited good photoelectrochemical performance with uniform potential distribution within the channels which served diffusion of neutral and charged species and electrochemical reaction. The maximum conversion of benzyl alcohol in this work was 48.25% with 100% selectivity of benzaldehyde. These findings are key for the design of the continuous-flow PEC reactor that can be applied to any series of biomass conversion reactions under mild conditions.