A solid-state integrated photo-supercapacitor based on ZnO nanorod arrays decorated with Ag(2)S quantum dots as the photoanode and a PEDOT charge storage counter-electrode

基于ZnO纳米棒阵列(表面修饰有Ag(2)S量子点)作为光阳极和PEDOT电荷存储对电极的固态集成光超级电容器

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Abstract

A planar solid-state photocapacitor with two electrodes has been prepared for the first time using a passivated film of ZnS with Ag(2)S quantum dots deposited on ZnO nanorods, which were electrochemically grown on ZnO seed layers, as the photoanode. The supercapacitor part is composed of a electrodeposited poly(3,4-ethylene-dioxythiophene) PEDOT film as the counter-electrode and an ionic liquid-based electrolyte between them deposited by the dip coating method. The different nanostructures and electrodes were morphologically and structurally characterized, and the device was electrochemically characterized and could reach a potential of 0.33 V during photocharge and a storage efficiency of 6.83%.

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