Ultrasonic processing of WO(3) nanosheets integrated Ti(3)C(2) MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation

超声处理WO(3)纳米片与Ti(3)C(2) MXene 2D-2D基异质结的集成,具有协同效应,可增强水分解和环境修复性能

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Abstract

This article describes a straightforward chemical procedure that involves hydrothermal and ultrasonic treatments to create a new 2D/2D ultrathin WO(3)/Ti(3)C(2) heterojunctions. The features of the fabricated heterojunctions were characterized and examined by field emission electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), optical absorption spectroscopy (UV-Vis). By photodegrading an organic dye under the influence of visible light, the photocatalytic degradation capabilities of the heterojunctions were also investigated. The performance of WO(3)/Ti(3)C(2) was superior to that of bare WO(3), with a removal rate of 94% and a kinetic rate constant (k) that was approximately 3 times that of WO(3). The creation of 2D/2D heterojunction was observed to encourage the spatial charge separation and increase the surface reactive sites, to result with the increased photocatalytic activity in WO(3)/Ti(3)C(2) heterojunction. The photocurrent values discovered through photoelectrochemical studies further indicated Ti(3)C(2)'s active function in enhancing water-splitting performance. The impedance analysis examined by an electrochemical method revealed that heterojunctions might be helpful in accelerating the migration of charges quickly to get the outcomes seen.

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