Synthesis of (FeCoNiCuMn)(3)O(4) spinel-high entropy oxide and green carbon from agricultural waste for supercapacitor application

利用农业废弃物合成(FeCoNiCuMn)3O4尖晶石型高熵氧化物和绿色碳材料,用于超级电容器

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Abstract

This article highlights (FeCoNiCuMn)(3)O(4) high-entropy oxide prepared via liquid state induction melting techniques for supercapacitor application. Nanostructured high entropy oxides have higher active sites to boost the surface redox process with transition metal cations, such as Fe(2+), Mn(3+), Ni(2+), Co(2+), and Cu(+), which helps to improve specific power, long-term cyclic stability, and specific capacitance. Melted and ball-milled HEA Nps were annealed to form the high entropy oxide, which uses a positive electrode for supercapacitor application; this results in the highest specific capacitance of 313 F g(-1) for a current rate of 5 mV s(-1) for the optimized 3 M KOH electrolyte. The biochar prepared through the pyrolysis of rice straw biochar shows a maximum specific capacitance of 232 F g(-1) for 5 mV s(-1). The fabricated aqueous devices display the highest specific capacitance of 83 F g(-1) at 2 A g(-1) with a specific energy of 33.4 W h kg(-1) at 1700 W kg(-1).

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