Abstract
Food waste has become a source of concern as it is generated abundantly worldwide and needs to be valorised into new products. In this study, cucumber, tomato, and carrot wastes were investigated as pyrolysis feedstocks as a single component (cucumber), a binary component mixture (cucumber and tomato), and a ternary component blend (cucumber, tomato, and carrot). Fourteen scenarios were simulated and evaluated based on varying the feedstock blend (single, binary, and tertiary), temperature (300 and 500 °C), and feedstock moisture content (5, 20, and 40%). Using an established empirical model, the effect of these parameters on product yields, techno-economic implications, energy requirements, and life cycle analysis (LCA) outcomes were investigated. The best performers of each scenario were determined, and their strengths and weaknesses were identified and compared with other scenarios. In terms of product yields, all three systems (single, binary, and tertiary) followed a similar pattern: bio-oil yields increased as temperature and feedstock moisture content increased, while biochar yields decreased as temperature and feedstock moisture content increased. The production of syngas, on the other hand, was only observed at elevated temperatures. The total energy requirement exhibited an increase with increasing temperature and feedstock moisture content. The economic evaluation revealed that the return on investment (ROI) value for the single component at 5% moisture content at 300 °C is 29%, with a payback period (PB) of only 3.4 years, which is potentially very appealing. The water footprint increased with increasing pyrolysis temperature but decreased with increasing moisture content in all scenarios. The land footprint is observed to remain constant despite changes in process conditions. The study's findings contribute to the pyrolysis process's scalability, technological advancement, and commercialisation.