Abstract
The formation process of Particulate Matter (PM) during sludge pyrolysis at different temperatures (300-700 °C) and the ecological risks of heavy metals were studied. The results showed that the particulate matter is mainly condensed on the quartz film in a carbon-based organic matter when the pyrolysis temperature was between 200-500 °C in a volatilization process. Inorganic particles was found in the particulate matter when the temperature was raised to 500-700 °C in a decomposition stage. Heavy metals were enriched in particulate matter with increase in pyrolysis temperature. When the temperature reached 700 °C, the concentration of Pb and Cd in the particulate matter significantly increased. The ecological risk assessment showed that heavy metals in the sewage sludge had considerable ecological toxicity. When the pyrolysis temperature reached 700 °C, the ecological toxicity of those heavy metals enriched in the particulate matter decreased considerably.