TiO(2) Decorated onto Three-Dimensional Carbonized Osmanthus Fragrans Leaves for Solar-Driven Clean Water Generation

将二氧化钛(TiO₂)修饰到三维碳化桂花叶片上,用于太阳能驱动的清洁水生成。

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Abstract

Solar steam generation (SSG) has garnered significant attention for its potential in water purification applications. While composites with physically combined structures based on semiconductors or biomass have been developed for SSG, there remains a critical need for low-cost, high-efficiency devices. In this study, TiO(2) composites exhibiting excellent stability, high solar absorption, porous microstructure, and hydrophilic surfaces were identified as effective materials for SSG and water purification for the first time. A novel SSG device was designed by decorating TiO(2) onto three-dimensional carbonized Osmanthus fragrans leaves (TiO(2)/carbonized OFL). Compared to directly carbonized OFL (without TiO(2)) and Osmanthus fragrans leaves with templated TiO(2) (OFL-templated TiO(2)), the TiO(2)/carbonized OFL carbon composites demonstrated enhanced solar absorption, achieving over 99% in the visible region and more than 80% in the near-infrared region. Under solar illumination of 1 kW·m(-2), the TiO(2)/carbonized OFL device achieved a high water evaporation rate of 2.31 kg·m(-2)·h(-1), which is 1.6 times higher than that of carbonized OFL and 3.45 times higher than OFL-templated TiO(2). Additionally, the TiO(2)/carbonized OFL system exhibited remarkable efficiency in treating pharmaceutical wastewater, with a chemical oxygen demand (COD) removal efficiency of 98.9% and an ammonia nitrogen removal efficiency of 90.8% under solar radiation.

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