Abstract
Compared with currently prevailing Li-ion technologies, sodium-ion energy storage devices play a supremely important role in grid-scale storage due to the advantages of rich abundance and low cost of sodium resources. As one of the crucial components of the sodium-ion battery and sodium-ion capacitor, electrode materials based on biomass-derived carbons have attracted enormous attention in the past few years owing to their excellent performance, inherent structural advantages, cost-effectiveness, renewability, etc. Here, a systematic summary of recent progress on various biomass-derived carbons used for sodium-ion energy storage (e.g., sodium-ion storage principle, the classification of bio-microstructure) is presented. Current research on the design principles of the structure and composition of biomass-derived carbons for improving sodium-ion storage will be highlighted. The prospects and challenges related to this will also be discussed. This review attempts to present a comprehensive account of the recent progress and design principle of biomass-derived carbons as sodium-ion storage materials and provide guidance in future rational tailoring of biomass-derived carbons.