(Ca(0).(25)La(0).(5)Dy(0).(25))CrO(3) Ceramic Fiber@Biomass-Derived Carbon Aerogel with Enhanced Solute Transport Channels for Highly Efficient Solar Interface Evaporation

(Ca(0).(25)La(0).(5)Dy(0).(25))CrO(3)陶瓷纤维@生物质衍生碳气凝胶,具有增强的溶质传输通道,用于高效太阳能界面蒸发

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Abstract

The use of solar interface evaporation for seawater desalination or sewage treatment is an environmentally friendly and sustainable approach; however, achieving efficient solar energy utilization and ensuring the long-term stability of the evaporation devices are two major challenges for practical application. To address these issues, we developed a novel ceramic fiber@bioderived carbon composite aerogel with a continuous through-hole structure via electrospinning and freeze-casting methods. Specifically, an aerogel was prepared by incorporating perovskite oxide (Ca(0).(25)La(0).(5)Dy(0).(25))CrO(3) ceramic fibers (CCFs) and amylopectin-derived carbon (ADC). The CCFs exhibited remarkable photothermal conversion efficiencies, and the ADC served as a connecting agent and imparted hydrophilicity to the aerogel due to its abundant oxygen-containing functional groups. After optimizing the composition and microstructure, the (Ca(0).(25)La(0).(5)Dy(0).(25))CrO(3) ceramic fiber@biomass-derived carbon aerogel demonstrated remarkable properties, including efficient light absorption and rapid transport of water and solutes. Under 1 kW m(-2) light intensity irradiation, this novel material exhibited a high temperature (48.3 °C), high evaporation rate (1.68 kg m(-2) h(-1)), and impressive solar vapor conversion efficiency (91.6%). Moreover, it exhibited long-term stability in water evaporation even with highly concentrated salt solutions (25 wt%). Therefore, the (Ca(0).(25)La(0).(5)Dy(0).(25))CrO(3) ceramic fiber@biomass-derived carbon aerogel holds great promise for various applications of solar interface evaporation.

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