Periodic splay Fréedericksz transitions in a ferroelectric nematic

铁电向列相中的周期性展开弗雷德里克斯转变

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Abstract

Electric field-induced splay of molecular orientation, called the Fréedericksz transition, is a fundamental electro-optic phenomenon in nonpolar nematic liquid crystals. In a ferroelectric nematic N(F) with a spontaneous electric polarization P , the splay is suppressed since it produces bound electric charges. Here, we demonstrate that an alternating current (ac) electric field causes three patterns of N(F) polarization. At low voltages, P oscillates around the field-free orientation with no stationary deformations. As the voltage increases, the polarization acquires stationary distortions, first splay and twist in a stripe pattern and then splay and bend in a square lattice of +1 and -1 defects. In all patterns, P oscillates around the stationary orientations. The stationary bound charge is reduced by a geometrical "splay cancellation" mechanism that does not require free ions: the charge created by splay in one plane is reduced by splay of an opposite sign in the orthogonal plane.

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