Abstract
Liquid crystal networks (LCN) have attracted surging interest as extraordinary energy-dissipation materials owning to their unique dissipation mechanism based on the re-orientation of mesogens. However, how to integrate high Young's modulus, good dissipation efficiency and wide effective damping temperature range in energy-dissipation LCN remains a challenge. Here, we report a strategy to resolve this challenge by fabricating robust energy-dissipation liquid crystal semi-interpenetrating polymer network (LC-semi-IPN) consisting crystalline LC polymers (c-LCP). LC-semi-IPN demonstrates a superior synergistic performance in both mechanical and energy-dissipation properties, surpassing all currently reported LCNs. The crystallinity of c-LCP endows LC-semi-IPN with a substantial leap in Young's modulus (1800% higher than single network). The chain reptation of c-LCP also promotes an enhanced dissipation efficiency of LC-semi-IPN by 200%. Moreover, its effective damping temperature reaches up to 130 °C, which is the widest reported for LCNs. By leveraging its exceptional synergistic performance, LC-semi-IPN can be further utilized as a functional architected structure with exceptional energy-dissipation density and deformation-resistance.