Abstract
The synthesis and characterization of a novel florescent chemosensor 1 with two different types of cationic binding sites have been reported in this work, which is a calix[4]crown derivative in 1,3-alternate conformation bearing two 2-phenyl-5-(4-dimethylaminopyenyl)-1,3,4-oxadiazole units. The recognition behaviors of 1 in dichloromethane/acetonitrile solution to alkali metal ions (Na(+) and K(+)), alkaline earth metal ions (Mg(2+) and Ca(2+)), and transition metal ions (Co(2+), Ni(2+), Zn(2+), Cd(2+), Cu(2+), Mn(2+), and Ag(+)) have been investigated by UV-Vis and fluorescence spectra. The fluorescence of 1 might be quenched selectively by Cu(2+) due to the photo-induced electron transfer mechanism, and the quenched emission from 1 could be partly revived by the addition of Ca(2+) or Mg(2+); thus, the receptor 1 might be worked as an on-off switchable fluorescent chemosensor triggered by metal ion exchange.