Development of Novel Integrin α(v)β(3)‑Targeted Radioligand for Enhanced Tumor Accumulation

开发新型整合素α(v)β(3)靶向放射性配体以增强肿瘤蓄积

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Abstract

Effective tumor delivery of radioligands is crucial for cancer diagnosis and therapy. Integrin α(v)β(3) is an attractive target for cancer treatment, and the development of integrin α(v)β(3)-targeted radioligands with high-level tumor accumulation is desired. Albumin binder (ALB) is a useful moiety to enhance tumor accumulation of radioligands. Furthermore, the introduction of dual amino acid linkers to an ALB-containing prostate-specific membrane antigen-targeted radioligand enhances the tumor accumulation by increasing its albumin-binding affinity. In this study, we newly developed two integrin α(v)β(3)-targeted radioligands: one containing both dual amino acid linkers and ALB ([(111)In]-In-RGD-DA6) and another containing only ALB ([(111)In]-In-RGD-DA1). In albumin-binding assays, [(111)In]-In-RGD-DA6 showed higher albumin-binding affinity than [(111)In]-In-RGD-DA1 and [(111)In]-In-DOTA-c-(RGDfK), a counterpart without dual amino acid linkers and ALB. In biodistribution studies, [(111)In]-In-RGD-DA6 also showed higher tumor accumulation than [(111)In]-In-RGD-DA1 and [(111)In]-In-DOTA-c-(RGDfK). These results highlight the potential of [(111)In]-In-RGD-DA6 as an integrin α(v)β(3)-targeted radioligand with enhanced tumor accumulation.

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