Abstract
Biomass-derived carbon quantum dots (CQDs) are attractive to serve as fluorescent nanosensors owing to their superior environmental compatibility and biocompatibility. However, the detection range has been limited, only in partial agreement with the experimental data. Thus, an advanced kinetic model for quantifying the fluorescence quenching over a wide range is on demand. Here, we describe a nanosensor for Fe(Ⅲ) detection in real waters, which is developed via microalgal residue-derived CQDs with an advanced kinetic model. The multiple-order kinetic model is established to resolve the incoherence of previous models and unveil the entire quenching kinetics. The results show that the detection range of Fe(Ⅲ) can reach up to 10 mM in the high detection end. The newly obtained kinetic model exhibits satisfactory fittings, clearly elucidating a dynamic quenching mechanism. This work provides a new insight into CQDs-based detection of heavy metals in real water samples by establishing an innovative multiple-order kinetic model.