Polyvinylidene Fluoride (PVDF)/Polyacrylonitrile (PAN)/Carbon Nanotube Nanocomposites for Energy Storage and Conversion

聚偏氟乙烯 (PVDF)/聚丙烯腈 (PAN)/碳纳米管纳米复合材料用于能量存储和转换

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作者:Salem M Aqeel, Zhongyuan Huang, Jonathan Walton, Christopher Baker, D'Lauren Falkner, Zhen Liu, Zhe Wang

Abstract

Polyvinylidene fluoride (PVDF)/Polyacrilonitrile (PAN)/Multiwalled nanotubes functionalized COOH (MWNT-COOH) nanocomposites with different contents of MWNTs were fabricated by using electrospinning and solution cast methods. The interaction of the MWNTs with the polymer blend was confirmed by a Fourier transform infrared (FTIR) spectroscopy study. The dispersion of the MWNTs in the polymer blend was studied by scanning electron microscopy. The impedance and electrical conductivity of PVDF-PAN/CNTs in a wide frequency range at different temperatures have been studied. The effect of the concentration of the filler on the conductivity of the polymer composite was discussed. Nanocomposites based on PVDF/PAN and MWNTs as filler, show a significant enhancement in the electrical conductivity as a function of temperature.

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