Comparison of titanium soaked in 5 M NaOH or 5 M KOH solutions

浸泡在 5 M NaOH 或 5 M KOH 溶液中的钛的比较

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作者:Christina Kim, Matthew R Kendall, Matthew A Miller, Courtney L Long, Preston R Larson, Mary Beth Humphrey, Andrew S Madden, A Cuneyt Tas

Abstract

Commercially pure titanium plates/coupons and pure titanium powders were soaked for 24 h in 5 M NaOH and 5 M KOH solutions, under identical conditions, over the temperature range of 37° to 90 °C. Wettability of the surfaces of alkali-treated cpTi coupons was studied by using contact angle goniometry. cpTi coupons soaked in 5 M NaOH or 5 M KOH solutions were found to have hydrophilic surfaces. Hydrous alkali titanate nanofibers and nanotubes were identified with SEM/EDXS and grazing incidence XRD. Surface areas of Ti powders increased > 50–220 times, depending on the treatment, when soaked in the above solutions. A solution was developed to coat amorphous calcium phosphate, instead of hydroxyapatite, on Ti coupon surfaces. In vitro cell culture tests were performed with osteoblast-like cells on the alkali-treated samples.

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