ZnO NRs/rGO Photocatalyst in a Polymer-Based Microfluidic Platform

基于聚合物的微流体平台中的 ZnO NRs/rGO 光催化剂

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作者:Aini Ayunni Mohd Raub, Ida Hamidah, Asep Bayu Dani Nandiyanto, Jaenudin Ridwan, Mohd Ambri Mohamed, Muhamad Ramdzan Buyong, Jumril Yunas

Abstract

This paper reports the development of ZnO NRs/rGO-based photocatalysts integrated into a tree-branched polymer-based microfluidic reactor for efficient photodegradation of water contaminants. The reactor system includes a photocatalytic reactor, tree-branched microfluidic channels, and ZnO nanorods (NRs) coated with reduced graphene oxide (rGO) on a glass substrate within an area of 0.6 × 0.6 cm2. The ZnO NRs/rGO acts as a photocatalyst layer grown hydrothermally and then spray-coated with rGO. The microfluidic system is made of PDMS and fabricated using soft lithography (micro molding using SU-8 master mold patterned on a silicon wafer). The device geometry is designed using AutoCAD software and the flow properties of the microfluidics are simulated using COMSOL Multiphysics. The microfluidic platform's photocatalytic process aims to bring the nanostructured photocatalyst into very close proximity to the water flow channel, reducing the interaction time and providing effective purification performance. Our functionality test showed that a degradation efficiency of 23.12 %, within the effective residence time of less than 3 s was obtained.

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