Entropy-Stabilized Oxides owning Fluorite Structure obtained by Hydrothermal Treatment

通过水热处理获得具有萤石结构的熵稳定氧化物

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作者:Luca Spiridigliozzi, Claudio Ferone, Raffaele Cioffi, Grazia Accardo, Domenico Frattini, Gianfranco Dell'Agli

Abstract

Entropy-Stabilized Oxides (ESO) is a modern class of multicomponent advanced ceramic materials with attractive functional properties. Through a five-component oxide formulation, the configurational entropy is used to drive the phase stabilization over a reversible solid-state transformation from a multiphase to a single-phase state. In this paper, a new transition metal/rare earth entropy-stabilized oxide, with composition Ce0.2Zr0.2Y0.2Gd0.2La0.2O2-, was found after several investigations on alternative candidate systems. X-Ray Diffraction (XRD) analyses of calcined powders pointed out different behavior as a function of the composition and a single-phase fluorite structure was obtained after a specific thermal treatment at 1500 °C. Powders presented the absence of agglomeration, so that the sintered specimen exhibited sufficient densification with a small porosity, uniformly distributed in the sample.

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