Melamine sponge-based copper-organic framework (Cu-CPP) as a multi-functional filter for air purifiers

三聚氰胺海绵基铜有机框架(Cu-CPP)作为空气净化器的多功能过滤器

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Abstract

COVID-19 has drawn great attention on the necessity for establishing pathogen-free indoor air. This paper offers an insight into the potential application of a multi-purpose filter to remove fine particulates and disinfect pathogens using melamine sponge with a copper-organic framework. In-situ growth dip coating method was applied to coat Cu-based coordination polymer particle (Cu-CPP) on melamine sponge (MS). The integration of Cu-CPPs with high crystallinity and highly active surface area (1,318.1 m(2)/g) enabled Cu-CPP/MS to have an excellent capture rate (99.66%) and an instant disinfection rate of 99.54% for Escherichia coli. Electrostatic attraction seemed to play a crucial role in capturing negative-charged pathogens effectively by positive charges on Cu-CPP arising from unbalanced copper ions in Cu-CPP. Disinfection of pathogens was mainly attributed to catalytically active Cu(2+) sites. Organic ligand played an important role in bridging and maintaining Cu(2+) ions within the framework. This study highlights the design of a new capture-and-disinfection (CDS) air filter system for pathogens using Cu-CPP/MS. It can be applied as a substitute for conventional high-efficiency particulate air (HEPA) filters. ELECTRONIC SUPPLEMENTARY MATERIAL: Supplementary material is available for this article at 10.1007/s11814-021-1000-4 and is accessible for authorized users.

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