Abstract
A series of group 13 complexes of the general type [{(WCA-IDipp)EX3 }Li(solv)] (E=B, Al, Ga, In; X=Cl, Br) that bear an anionic N-heterocyclic carbene ligand with a weakly coordinating borate moiety (WCA-IDipp, WCA=B(C6 F5 )3 and IDipp=1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) were prepared by the reaction of the respective group 13 trihalides (EX3 ) with the lithium salt [(WCA-IDipp)Li ⋅ toluene]. The molecular structures of the BBr3 , AlCl3 , AlBr3 , GaCl3 and InCl3 adducts were established by X-ray diffraction analyses, revealing the formation of coordination polymers linked by halide-lithium interactions, except for the indium derivative, which consists of isolated [Li(THF)4 ]+ and [(WCA-IDipp)InCl3 ]- ions in the solid state.