Zinc(II) Coordination Compounds on Acylhydrazones of 2-Tosylaminobenzaldehyde Basis as Promising Luminescent Agents

基于2-甲苯磺酰氨基苯甲醛酰腙的锌(II)配位化合物作为有前景的发光剂

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Abstract

Five zinc(II) complexes based on N-[[2-(p-tolylsulfonylamino)-phenyl]-methyleneamino]-4R-benzamides were synthesized and characterized by elemental analysis, ESI-MS, FT-IR, (1)H NMR and single-crystal X-ray analysis. Crystallographic studies reveal that the complexes have a polymer structure in the solid state. Acylhydrazones and zinc(II) complexes demonstrate effective photoluminescence in solutions and in the solid state. Preliminary studies have shown that the studied complexes can be used as emitters in OLED devices and for the bioimaging of pathogenic processes at the cellular level.

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