Prussian Blue Anchored on Reduced Graphene Oxide Substrate Achieving High Voltage in Symmetric Supercapacitor

普鲁士蓝锚定在还原氧化石墨烯基底上,在对称超级电容器中实现高电压

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作者:Lindiomar Borges Avila, Pablo A Serrano, Luis Torres Quispe, Adriana Dantas, Diogo Pontes Costa, Edy Elar Cuevas Arizaca, Diana Patricia Paredes Chávez, César Daniel Valdivia Portugal, Christian Klaus Müller

Abstract

In this work, iron hexacyanoferrate (FeHCF-Prussian blue) particles have been grown onto a reduced graphene oxide substrate through a pulsed electrodeposition process. Thus, the prepared FeHCF electrode exhibits a specific volumetric capacitance of 88 F cm-3 (specific areal capacitance of 26.6 mF cm-2) and high cycling stability with a capacitance retention of 93.7% over 10,000 galvanostatic charge-discharge cycles in a 1 M KCl electrolyte. Furthermore, two identical FeHCF electrodes were paired up in order to construct a symmetrical supercapacitor, which delivers a wide potential window of 2 V in a 1 M KCl electrolyte and demonstrates a large energy density of 27.5 mWh cm-3 at a high power density of 330 W cm-3.

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