Nanofiber NiMoO4/g-C3N4 Composite Electrode Materials for Redox Supercapacitor Applications

用于氧化还原超级电容器应用的纳米纤维 NiMoO4/g-C3N4 复合电极材料

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作者:Kannadasan Thiagarajan, Thirugnanam Bavani, Prabhakarn Arunachalam, Seung Jun Lee, Jayaraman Theerthagiri, Jaganathan Madhavan, Bruno Georges Pollet, Myong Yong Choi

Abstract

NiMoO4/g-C3N4 was fabricated by a hydrothermal method and used as an electrode material in a supercapacitor. The samples were characterized by XRD, FTIR, scanning electron microscopy (SEM) and transmission electron microscopy (TEM) to study the physical and structural properties of the as-prepared NiMoO4/g-C3N4 material. The electrochemical responses of pristine NiMoO4 and the NiMoO4/g-C3N4 nanocomposite material were investigated by cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) and electrochemical impedance spectroscopy (EIS). From the CD studies, the NiMoO4/g-C3N4 nanocomposite revealed a higher maximum specific capacitance (510 Fg-1) in comparison to pristine NiMoO4 (203 Fg-1). In addition, the NiMoO4/g-C3N4 composite electrode material exhibited high stability, which maintained up to 91.8% capacity even after 2000 charge-discharge cycles. Finally, NiMoO4/g-C3N4 was found to exhibit an energy density value of 11.3 Whkg-1. These findings clearly suggested that NiMoO4/g-C3N4 could be a suitable electrode material for electrochemical capacitors.

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