Data for the synthesis of β-oxopropylcarbamates from propargylic alcohols, secondary amines and CO(2) catalyzed by a recyclable AgBr/ionic liquid system under ambient pressure

本文报道了在常压下,以可循环利用的AgBr/离子液体体系为催化剂,由炔丙醇、仲胺和CO₂合成β-氧代丙基氨基甲酸酯的反应数据。

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Abstract

Data presented here are related with the research article entitled "Synthesis of ß -oxopropylcarbamates in a recyclable AgBr/ionic liquid catalytic system: An efficient assembly of CO(2) under ambient pressure" (Song et al., 2018) [1]. In this data article, the general synthetic procedures of ß-oxopropylcarbamates through the three-component reaction of propargylic alcohols, secondary amines and carbon dioxide (CO(2)) catalyzed by a recyclable AgBr/ionic liquid (IL) system under mild pressure are described. Furthermore, the process for recycling the catalysts is supplied as well. Specifically, the investigative data for the temperature, amount of ILs, reaction time as well as the state of silver in the system are also reported. Finally, all the target products are confirmed by (1)H NMR, (13)C NMR, and high-resolution mass spectroscopy (HR-MS).

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