Abstract
Download ash and emission dust samples were collected from sintering, coking, ironmaking and steelmaking processes of iron and steel enterprises in Laiwu. Sixteen kinds of polycyclic aromatic hydrocarbons (PAHs) in the United States Environmental Protection Agency (USEPA) priority controlled lists were quantitatively analyzed using Gas Chromatography-Mass Spectrometer (GC-MS). Laser particle size analyzer was used to obtain the distribution pattern of download ash. It was found that the diameter distribution pattern from four production processes was quite different. The proportion of fine particulate (0-2.5 μm) was the highest (72.62%) in the steelmaking refining process, and was 28.962% in the ironmaking process. Moreover, the particle size in download ash from steelmaking refining is all less than 10 μm and that from the ironmaking process was 52.92%. The medium-sized particles (10-100 μm) were dominant in sinter and coking download ashes. The total PAHs (∑(16)PAHs) mass concentration ranged from 0.49 ± 0.06 to 69.63 ± 5.57 μg·g(-1) in download ash samples, and varied from 2.815 ± 0.253 to 19.429 ± 2.545 μg·m(-3) in emission dust samples. The ∑(16)PAHs values were both largest in download ash and dust emission from the coking process (69.63 ± 5.57 μg·g(-1) and 19.429 ± 2.545 μg·m(-3), respectively). The most abundant individual PAHs were benzo[b]fluoranthene, benzo[k]fluoranthene, phenanthrene, benzo[a]anthracene in ash samples, and benzo[a]anthracene, benzo[k]fluoranthene, benzo[b]fluoranthene and indeno[1,2,3-cd]pyrene in emission dust samples. Dominant compounds were high-molecular weight (four- to six-ring) PAHs in both ash and dust samples. The concentration order of individual compounds in PM(10) and PM(2.5) in ambient air around the steel plant was completely consistent with each other, and the concentration of ∑(16)PAHs was the highest in the steel plant and lowest in Daqin village because of upwind of the steel plant. The concentrations of benzo[b]fluoranthene and fluoranthene in ambient air were comparatively high, and were in accordance with the higher concentration of the two monomers in the download ash samples, which suggested that the effect of the emission flue gas from the steel plant on ambient air was necessary to concern.